Hydrogen embrittlement he also known as hydrogen assisted cracking hac and hydrogeninduced cracking hic, describes the embrittling of metal after being exposed to hydrogen. Sulfide stress cracking is also called hydrogen sulfide cracking, sulfide cracking, sulfide corrosion cracking and sulfide stresscorrosion cracking. H2s causes severe corrosion to copper, silver, brass and bronze. The letter in conjunction with the number designates parameters such as the maximum yield strength and the minimum ultimate strength which for l80 pipe are 95,000 psi.
Sulfide stress cracking how is sulfide stress cracking abbreviated. Carbide on reheat cracking sensitivity of crmo steels, iiw doc. Sulfide stress cracking is a function of hydrogen sulfide concentration as low as ppm, hydrogen sulfide partial pressure, stresses, material yield strength, temperature and ph. For this reason, along with toxicity risks of hydrogen sulfide gas, it is essential that water muds be kept entirely free of soluble sulfides and especially hydrogen sulfide at low ph. It can occur when carbonsteel equipment becomes exposed to wet h 2 s service environments, and it can come in several different forms. Wet hydrogen sulfide h2s cracking inspectioneering. Below 20f 7c the diffusion rate of the hydrogen is so slow that the critical concentration is never reached. Sulfide stress cracking nace mr01752002, mr0175iso. Sulfide stress cracking ssc also known as sour gas cracking sour gas. Worlds best powerpoint templates crystalgraphics offers more powerpoint templates than anyone else in the world, with over 4 million to choose from. As we know that both form of cracking are due to the absorption of atomic hydrogen that is produced by. Sulfide stress cracking is also called hydrogen sulfide cracking, sulfide cracking, sulfide corrosion cracking and. Sulfide stress cracking nace mr01752002, mr0175iso 15156.
Sulfide stress cracking resistant steels for heavy section wellhead. It should not be confused with the term stress corrosion cracking which is an anodic cracking mechanism. Field history the production unit is installed as close to the oil wells as possible and is used to separate gas and water from the crude oil. An industry value that has been developed is nace mr01. Recent experience has demonstrated the risk of sscc and hic, sometimes known as hydrogen embrittlement he, of low strength steels subject to high residual stress derived from fabrication techniques. The major hazards of h 2 s are its ability to cause rapid damage to health or sudden death due to accidental exposure and metal integrity failure due to general corrosion or cracking. Covers sulfide stress cracking room temperature, atmospheric pressure and stress corrosion cracking elevated temperatures and pressures. Evaluating the suitability of the nace standard test, tm 01 77, for. Materials not susceptible to h2s stress cracking may be used. Wet h 2 s corrosion can be a particularly dangerous form of corrosion because damage caused by it takes place on the interior of.
Effect of carbon migration on sulfide stress corrosion. The list of acronyms and abbreviations related to ssc sulfide stress cracking. Winner of the standing ovation award for best powerpoint templates from presentations magazine. Corrosionpedia what is sulfide stress cracking ssc. The sulfide stress cracking fracture toughness is primarily a function of alloy composition and microstructure. Sulfide stress cracking of stainless steel 410 in sour. Partial pressure of the h 2 s is determined by multiplying the mole fraction of h 2 s in the gas by the total pressure. Types of environmental cracking stress corrosion cracking scc sulfide stress cracking chloride induced scc caustic induced scc hydrogen embrittlement corrosion fatigue cracks the cracks form and propagate approximately at right angles to the direction of the tensile stresses at stress levels much lower than those required to fracture the. Sulfide stress cracking resistant steels for heavy section. Ongoing work to change specification to accept explosion clad material without. The development of low alloy steels for heavy section wellhead equipment which will be subject to hydrogen sulfide stress corrosion cracking ssc is described. Sulfide stress cracking of nickelcontaining lowalloy steels. This article describes current industry practices to catalog features observed after sulfide stress cracking testing.
To protect from ssc, hic hydrogen induced cracking and other damage mechanisms, refiners use a variety of defenses. Amine cracking is often intertwined with wet hydrogen sulfide h2s and carbonate cracking, as amines, carbonates and wet sulfides often exist together in amine. This article is reporting the sulfide stress cracking of stainless steel 410 in annealed condition. Sulfide stress cracking ssc vs hydrogen induced cracking. Discusses environment cracking variability, test reagents and solutions, material properties, test vessels and fixtures, and testing at elevated temperaturepressure. Standard material requirements sulfide stress cracking. Alloys which are commercially available and those which have modified metallurgical structures and. Tib and mncrmo was evaluated using constant load tensile test.
Overview of ngv fuel tank testing requirements livio gambone, p. The embrittlement induced by ssc causes failure of steel at a stress level, which is significantly lower than its yield strength. Nace mr 0103 materials resistant to sulfide stress cracking in corrosive petroleum refining. Sulfide stress cracking is most severe at ambient temperature, 20 to 120f 7 to 49c. Most serious type of stress corrosion cracking due to hydrogen occurs in sour service hydrogen usually picked up from sulfide solutions. Producing wet sour gas presents some of the toughest technical challenges in the oil and gas business. The h2s causes the hydrogen to enter the metal structure rather than bubble off from the surface. The ssc of medium strength steels has been a continuing source of trouble in the oil fields, and from these troubles has evolved in international standards 6. H2s also reacts with the iron in steel to form the potentially dangerous compounds iron pyrite and iron sulfide. In other words, it can support a stress of 80,000 psi with an elongation of less than 0.
Sulfide stress cracking ssc resistance of casing steels with different alloying chemistries i. Sulfide stress cracking an overview sciencedirect topics. In this chapter the terms eac and scc are generally interchangeable. Bismillahirrahmanirrahiiim sulfide stress corrosion cracking by hamdzan asat definition stresscorrosion crack scc is a crack which may be intergranular or transgranular depending on the material, resulting from the combined action of corrosion and stress, either external applied or internal residual.
It is a complex process that is not completely understood because of the variety and complexity of mechanisms that can lead to embrittlement. A much smaller sulfide content with high ph and dissolved cyanide, or. Sulfide stress cracking mostly occurs in very highly acidic environments. It is a progressive type of failure that produces cracking at stress levels that are well below the materials tensile strength. For example, cold worked brass, which is found in ammunition cartridges, is susceptible to stress corrosion cracking when exposed to an environment containing ammonia.
Other factors, such as ph, chloride concentration, and temperature also affect the potential for steel cracking. There are maximum acceptable h 2 s concentration limits in sale quality oil and gas, which require. Hydrogen sulfide is a colorless, very poisonous, flammable gas with the characteristic foul odor of rotten eggs. Corrosion process and control tkk2289 ppt video online. Sulfide stress cracking ssc has been the subject of investigation since the late 1940s, when a mysterious form of brittle failure began to be observed in steel equipment used to produce oil and.
Ssc is a form of spontaneous brittle breakdown in occurring in highstrength. Pdf sulfide stress corrosion cracking and hydrogen. The article also introduces a quantitative criterion to determine the maximum allowable defect size based on fracture mechanics principles. Sulfide stress cracking ssc of high strength, low alloy steel is a phenomenon of particular concern to the oil and gas industry 3. Sulfide stress crackingnace mr01752002, mr0175iso 15156 651 te c h n i c a l new sulfide stress cracking standard for refineries don bush, principal engineer materials, at emerson process management fisher valves, is a member and former chair of a nace task group that has written a document for refinery applications, nace mr0103. Processes or conditions involving wet hydrogen sulfide, i. The continuous cooling transformation behavior of nine steels was evaluated by dilatometry. Astm e 7, standard terminology relating to metallography stresscorrosion. The cooling water contained approximately 400 ppm chlorides had been blocked in with the 350f shellside process still flowing. Double cantilever beam fracture mechanics tests were used to evaluate the ssc resistance of twentyone quenched and tempered. In chloride containing environments, titanium alloys, aluminum alloys, and high strength stainless steels are susceptible and specific alloys. Tm01772016, laboratory testing of metals for resistance to sulfide stress cracking and stress corrosion cracking in h2s environments sorry this product is no longer available testing of metals subjected to tensile stresses for resistance to cracking failure in lowph aqueous environments containing hydrogen sulfide h2s. Sulfide stress cracking how is sulfide stress cracking. Sulfide stress cracking ssc is a type of hydrogen cracking which presents a cathodic embrittlement mechanism.
This penetration can lead to the brittle fracture of materials that are normally ductile when hydrogen happens to be present in their environment. The effect of quenching temperature, t q, on the sulfide stress cracking ssc behaviors was estimated via the double cantilever beam dcb and the electrochemical hydrogen permeation ehp. Sulfide stress cracking is a form of hydrogen embrittlement that occurs in highstrength steels and in localized hard zones in weldment of susceptible materials. Hydrogen stress cracking is a form of hydrogen embrittlement that occurs when corrosion from acids like wet hydrogen sulfide and hydrofluoric acid cause atomic hydrogen to penetrate hardened or higher strength steels and cause stress cracking. The resistance to chlorideinduced stress corrosion cracking of uns n08031 was tested on ubend specimens according to astm g 30 for a testing time of 2000 hours. H 2 s can cause corrosion of stainless steels such as 316 and 410 stainless in the form of sulfide stress cracking. Remember to always keep your buddy in sight while in the danger zone. Sulfide stress cracking steelsulfide stress cracking steel tensile steelaluminumplastic. Sulphide stress cracking ssc is the biggest concern 9. Hydrogen induced cracking of low strength steels in. Sulfide stress cracking ssc vs hydrogen induced cracking hlc posted in refining, hydrocarbons, oil, and gas. Ssc quickly diminishes performance of downhole tubulars.
Sulfide stress cracking ssc is a form of hydrogen embrittlement which is a cathodic cracking mechanism. Above those limits, the service is considered subject to stress corrosion cracking. Sulfide stress cracking ssc is one of the detrimental types of corrosion which happens in sour environment. This term should not be confused with stress corrosion cracking scs, since this is anodic in nature. Sulfide stress corrosion cracking and hydrogen induced cracking of a216wcc wellhead flow control valve body article pdf available in case studies in engineering failure analysis. Ppt hydrogen sulfide gas powerpoint presentation free. A small partial pressure of gaseous h2s with a system also containing free water. Environmentally assisted cracking eac is a general term that includes processes such as stress corrosion cracking scc, hydrogen embrittlement he, sulfide stress cracking ssc, liquid metal embrittlement lme, and corrosion fatigue cf. Standard material requirements sulfide stress cracking resistant metallic materials for oilfield equipment contents 1. To check its resistance to scc and ssc, several tests were performed.
Stresscorrosion cracking stresscorrosion cracking is caused by the presence of tensile stresses and a corrosive environment types of stresscorrosion cracking include ammonium embrittlement of copper alloys, caustic embrittlement of steels forms of corrosion typical corrosive white water compositions paper making environments. Effect of quenching temperature on sulfide stress cracking. One of the more common problems is ssc, sulfide stress cracking. Theyll give your presentations a professional, memorable appearance the kind of sophisticated look that todays audiences expect. Basics of sulfide stress cracking ssc and stress corrosion cracking scc ssc and scc are cracking processes that develop in the presence of water, corrosion and surface tensile stress. Sulfide stress cracking of pipelinecase history onepetro. Sulfide stress cracking is the worst type of corrosion in the presence of hydrogen sulfide. Sulfide stress crackingresistant drill pipe addresses h2s. Sulfide stress cracking is a form of hydrogen embrittlement that occurs in high strength steels and in localized hard zones in weldment of susceptible materials. The effect of applied potential on the sulfide stress cracking ssc of this material. The results showed that the resistance to sscc of this joint improved first then decline after 98h aging treatments. Sulfide stress cracking of nickelcontaining lowalloy steels in.
The stress corrosion cracking behaviour of uns n08031 in. Susceptible alloys, especially steels, react with hydrogen sulfide, forming metal sulfides and atomic hydrogen as corrosion byproducts. Stress corrosion cracking of stainless steels in highpressure. The utilization of brass connections and other equipment consisting of brass or bronze alloys are not recommended by the rrc. In this paper, mechanical performance test, slow strain rate test ssrt and optical microscopy analysis were employed in studying the effect of carbon migration on sulfide stress corrosion cracking sscc behaviors of cr5moa3020cr18ni9 dissimilar joints.
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